全文获取类型
收费全文 | 2949篇 |
免费 | 56篇 |
国内免费 | 75篇 |
专业分类
化学 | 394篇 |
晶体学 | 1篇 |
力学 | 109篇 |
综合类 | 3篇 |
数学 | 2201篇 |
物理学 | 372篇 |
出版年
2024年 | 2篇 |
2023年 | 41篇 |
2022年 | 56篇 |
2021年 | 35篇 |
2020年 | 42篇 |
2019年 | 36篇 |
2018年 | 51篇 |
2017年 | 50篇 |
2016年 | 44篇 |
2015年 | 48篇 |
2014年 | 108篇 |
2013年 | 176篇 |
2012年 | 241篇 |
2011年 | 169篇 |
2010年 | 130篇 |
2009年 | 222篇 |
2008年 | 244篇 |
2007年 | 189篇 |
2006年 | 135篇 |
2005年 | 87篇 |
2004年 | 71篇 |
2003年 | 83篇 |
2002年 | 50篇 |
2001年 | 52篇 |
2000年 | 35篇 |
1999年 | 46篇 |
1998年 | 59篇 |
1997年 | 56篇 |
1996年 | 52篇 |
1995年 | 44篇 |
1994年 | 36篇 |
1993年 | 30篇 |
1992年 | 27篇 |
1991年 | 27篇 |
1990年 | 22篇 |
1989年 | 14篇 |
1988年 | 17篇 |
1987年 | 10篇 |
1986年 | 17篇 |
1985年 | 35篇 |
1984年 | 26篇 |
1983年 | 22篇 |
1982年 | 32篇 |
1981年 | 22篇 |
1980年 | 25篇 |
1979年 | 14篇 |
1978年 | 32篇 |
1977年 | 8篇 |
1976年 | 4篇 |
1975年 | 2篇 |
排序方式: 共有3080条查询结果,搜索用时 15 毫秒
1.
Xingfei Xiang 《Journal of Mathematical Analysis and Applications》2022,505(2):125518
In bounded convex domains, the regularity of a vector field u with its , in space and the tangential component or the normal component of u over the boundary in space, is established for . As an application, we derive an estimate for solutions to a Maxwell type system with an inhomogeneous boundary condition in convex domains. In contrast to the well-posed region of r in the space for the Maxwell type system in Lipschitz domains given by Kar and Sini (2016) [16], we extend the well-posed region to be optimal. 相似文献
2.
《Operations Research Letters》2022,50(5):541-547
We consider two-stage recourse models with integer restrictions in the second stage. These models are typically non-convex and hence, hard to solve. There exist convex approximations of these models with accompanying error bounds. However, it is unclear how these error bounds depend on the distributions of the second-stage cost vector q. In this paper, we derive parametric error bounds whose dependence on the distribution of q is explicit: they scale linearly in the expected value of the -norm of q. 相似文献
3.
A Hjelmslev quadrilateral is a quadrilateral with two right angles at opposite vertices. Using mutual distances as coordinates, we show that any four-body central configuration forming a Hjelmslev quadrilateral must be a right kite configuration. 相似文献
4.
Eric C. Chi Liuyi Hu Arvind K. Saibaba Arvind U. K. Rao 《Journal of computational and graphical statistics》2019,28(1):36-47
We consider the problem of performing matrix completion with side information on row-by-row and column-by-column similarities. We build upon recent proposals for matrix estimation with smoothness constraints with respect to row and column graphs. We present a novel iterative procedure for directly minimizing an information criterion to select an appropriate amount of row and column smoothing, namely, to perform model selection. We also discuss how to exploit the special structure of the problem to scale up the estimation and model selection procedure via the Hutchinson estimator, combined with a stochastic Quasi-Newton approach. Supplementary material for this article is available online. 相似文献
5.
酚醛树脂是一种广泛使用的合成树脂,包括热固性和热塑性两类,具有良好的阻燃性、耐热性和耐腐蚀性。酚醛纤维是由酚醛树脂所制成的交联纤维,传统的酚醛纤维制备方法有熔融纺丝法和湿法纺丝法,后来出现了静电纺丝法。本文根据酚醛树脂的种类分别介绍了热固性、热塑性和热塑/热固混合酚醛树脂三类材料静电纺丝的研究进展。在改善酚醛纤维特性方面,综述了四种优化措施,包括加入无机盐、微波辐射辅助固化、非匀速阶梯式加热固化、氧化石墨烯修饰的静电纺丝法等。此外,对本实验室制备酚醛纤维的研究也进行了概述,阐述了酚醛纤维当前存在的问题及未来发展方向。 相似文献
6.
ABSTRACT The theory of calculus of variations is a mathematical tool which is widely used in different scientific areas in particular in physics and chemistry. This theory is strongly related with optimisation. In fact the former seeks to optimise an integral related with some physical magnitude over some space to an extremum by varying a function of the coordinates. On the other hand, reaction paths and potential energy surfaces, in particular their stationary points, are the basis of many chemical theories, in particular reactions rate theories. We present a review where it is gathered together the variational nature of many types of reaction paths: steepest descent, Newton trajectories, artificial force induced reaction (AFIR) paths, gradient extremals, and gentlest ascent dynamics (GAD) curves. The variational basis permits to select the best optimisation technique in order to locate important theoretical objects on a potential energy surface. 相似文献
7.
《Stochastic Processes and their Applications》2020,130(5):2954-2973
We consider a stochastic search model with resetting for an unknown stationary target with known distribution . The searcher begins at the origin and performs Brownian motion with diffusion constant . The searcher is also armed with an exponential clock with spatially dependent rate , so that if it has failed to locate the target by the time the clock rings, then its position is reset to the origin and it continues its search anew from there. Denote the position of the searcher at time by . Let denote expectations for the process . The search ends at time . The expected time of the search is then . Ideally, one would like to minimize this over all resetting rates . We obtain quantitative growth rates for as a function of in terms of the asymptotic behavior of the rate function , and also a rather precise dichotomy on the asymptotic behavior of the resetting function to determine whether is finite or infinite. We show generically that if is of the order , with , then is of the order ; in particular, the smaller the asymptotic size of , the smaller the asymptotic growth rate of . The asymptotic growth rate of continues to decrease when with ; now the growth rate of is more or less of the order . Note that this exponent increases to when increases to and decreases to 2 when decreases to 1. However, if , then , for . Our results suggest that for many distributions supported on all of , a near optimal (or optimal) choice of resetting function in order to minimize will be one which decays quadratically as for some . We also give explicit, albeit rather complicated, variational formulas for . For distributions with compact support, one should set off of the support. We also discuss this case. 相似文献
8.
Wireless Sensor Networks (WSN) are widely used in recent years due to the advancements in wireless and sensor technologies. Many of these applications require to know the location information of nodes. This information is useful to understand the collected data and to act on them. Existing localization algorithms make use of a few reference nodes for estimating the locations of sensor nodes. But, the positioning and utilization of reference nodes increase the cost and complexity of the network. To reduce the dependency on reference nodes, in this paper, we have developed a novel optimization based localization method using only two reference nodes for the localization of the entire network. This is achieved by reference nodes identifying a few more nodes as reference nodes by the analysis of the connectivity information. The sensor nodes then use the reference nodes to identify their locations in a distributive manner using Artificial Hummingbird Algorithm (AHA). We have observed that the localization performance of the reported algorithm at a lower reference node ratio is comparable with other algorithms at higher reference node ratios. 相似文献
9.
Dongfang Cheng Ziyang Wei Zisheng Zhang Prof. Peter Broekmann Prof. Anastassia N. Alexandrova Prof. Philippe Sautet 《Angewandte Chemie (International ed. in English)》2023,62(20):e202218575
The dynamic restructuring of Cu surfaces in electroreduction conditions is of fundamental interest in electrocatalysis. We decode the structural dynamics of a Cu(111) electrode under reduction conditions by joint first-principles calculations and operando electrochemical scanning tunneling microscopy (ECSTM) experiments. Combining global optimization and grand canonical density functional theory, we unravel the potential- and pH-dependent restructuring of Cu(111) in acidic electrolyte. At reductive potential, Cu(111) is covered by a high density of H atoms and, below a threshold potential, Cu adatoms are formed on the surface in a (4×4) superstructure, a restructuring unfavorable in vacuum. The strong H adsorption is the driving force for the restructuring, itself induced by the electrode potential. On the restructured surface, barriers for hydrogen evolution reaction steps are low. Restructuring in electroreduction conditions creates highly active Cu adatom sites not present on Cu(111). 相似文献
10.
João M. Leça Ana C. Pereira Ana C. Vieira Marco S. Reis José C. Marques 《Analytica chimica acta》2015
Vicinal diketones, namely diacetyl (DC) and pentanedione (PN), are compounds naturally found in beer that play a key role in the definition of its aroma. In lager beer, they are responsible for off-flavors (buttery flavor) and therefore their presence and quantification is of paramount importance to beer producers. Aiming at developing an accurate quantitative monitoring scheme to follow these off-flavor compounds during beer production and in the final product, the head space solid-phase microextraction (HS-SPME) analytical procedure was tuned through experiments planned in an optimal way and the final settings were fully validated. Optimal design of experiments (O-DOE) is a computational, statistically-oriented approach for designing experiences that are most informative according to a well-defined criterion. This methodology was applied for HS-SPME optimization, leading to the following optimal extraction conditions for the quantification of VDK: use a CAR/PDMS fiber, 5 ml of samples in 20 ml vial, 5 min of pre-incubation time followed by 25 min of extraction at 30 °C, with agitation. The validation of the final analytical methodology was performed using a matrix-matched calibration, in order to minimize matrix effects. The following key features were obtained: linearity (R2 > 0.999, both for diacetyl and 2,3-pentanedione), high sensitivity (LOD of 0.92 μg L−1 and 2.80 μg L−1, and LOQ of 3.30 μg L−1 and 10.01 μg L−1, for diacetyl and 2,3-pentanedione, respectively), recoveries of approximately 100% and suitable precision (repeatability and reproducibility lower than 3% and 7.5%, respectively). The applicability of the methodology was fully confirmed through an independent analysis of several beer samples, with analyte concentrations ranging from 4 to 200 g L−1. 相似文献